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Lower costs for converting alkylation units from hydrofluoric to sulfuric acid

For petroleum refineries, the cost of converting hydrofluoric-acid-based alkylation units to the relatively safer sulfuric-acid-based alkylation process (diagram) has been cost-prohibitive and has lacked specific economic benefits. Now, DuPont (Wilmington, Del.; www.dupont.com) has developed a low-cost approach to converting existing…

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Extremophilic microbes enable new methane pathways

Microbes inhabiting the extreme environments thousands of feet below the earth’s surface possess unique properties not encountered elsewhere. A research consortium of South Dakota School of Mines and Technology (SDSMT; Rapid City; www.sdsmt.edu), University of Oklahoma (Norman) and Montana State…

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A new C2-based production route to MMA

Chemists and engineers from the Performance Materials Segment of Evonik Industries AG (Essen, Germany; www.evonik.com) have developed a new process for making methyl methacrylate (MMA). With a yield of over 90%, the so-called Leading in Methacrylates (LiMA) process can be…

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Multilayer membrane for climate control

A triple-layer, porous membrane system developed at the Functional Materials Laboratory at Eidgenössische Technische Hochschule Zürich (www.fml.ethz.ch) can be fashioned into evaporative curtains to cool and humidify indoor spaces, potentially decreasing the energy demand for climate-control systems. Juxtaposing opposite forces…

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‘Deep-learning-based’ AI quickly predicts furnace products

NTT Communications Corp. (NTT Com; www.ntt.com) and Mitsui Chemicals Inc. (both Tokyo, Japan; www.mitsuichem.com) have demonstrated the ability to predict, with a high precision, the concentration of gaseous products generated in a furnace. The predictions are produced in just 20…

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A mag-drive pump that handles suspended solids

In critical pumping applications involving toxic or expensive products, the use of double mechanical seals or external flushing fluids can lead to product contamination or leakage, as well as additional costs for installation and monitoring. Although hermetically-sealed pumps, such as…

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Chementator Briefs

DPC monomer As part of an NEDO project, Asahi Kasei Corp. (Tokyo, Japan; www.asahi-kasei.co.jp) verified a newly developed process for diphenyl carbonate (DPC), a monomer used to produce polycarbonate (PC) at its Mizushima Works (Kurashiki, Okayama). The stability and operability…

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Extracting lithium without roasting

Lithium Australia NL (Perth, Western Australia; lithium-au.com) has generated 99.8% (battery-grade) lithium carbonate from lithium-bearing silicates, such as spodumene, using its Sileach process — a hydrometallurgical process that does not require an energy-intensive roasting step. The company says Sileach has…

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Making graphene from graphite without oxidation

Graphene can be produced and isolated by exfoliating graphite, but existing processes are difficult and expensive. The most common method involves aggressive oxidation of graphite and results in diminished properties and added expense. Another approach — mechanical exfoliation — requires…

Accelerated decomposition of halogenated compounds

A new research partnership between the Water Environment & Reuse Foundation (WERF; Alexandria, Va.; www.werf.org) and the University of Texas at Arlington (UTA; www.uta.edu) seeks to tackle one of the most challenging and persistent water contaminants — perfluorooctane sulfonate (PFOS).…