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Waste to chemicals A consortium of companies, including Air Liquide (Paris, France; www.airliquide.com), AkzoNobel Specialty Chemicals (Amsterdam, the Netherlands; www.akzonobel.com), Enerkem Inc. (Montreal, Canada; www.enerkem.com) and the Port of Rotterdam, has signed a project development agreement covering initial investments in…

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These batteries can handle the cold

Lithium-ion batteries based on intercalation compound electrodes exhibit poor performance at temperatures below 0°C. Insufficient ionic conductivity and freezing of the electrolyte are generally seen as the main reasons for the poor performance of rechargeable batteries at low temperatures. Although…

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A more direct chemical route to ketones

Using a simple, ligand-free palladium catalyst system, researchers at McGill University (Montreal, Que., Canada; www.mcgill.ca) have demonstrated that metal carbonylation — a core chemical reaction for many industrial products — can be used to synthesize ketones directly from hydrocarbons. The…

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A push for ‘green’ steel

Last month, the so-called Hybrit initiative (www.hybritdevelopment.com) was given the go-ahead to build a pilot plant for making fossil-free steel. The announcement follows a pre-feasibility study conducted by Swedish partners SSAB AB (Stockholm; www.ssab.com), LKAB (Luleå; www.lkab.com) and Vattenfall AB…

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‘One-pot’ synthesis of conjugated polyenes

The research group of professor Masafumi Hirando at Tokyo University of Agriculture and Technology (TUAT; Koganei City, Japan; www.tuat.ac.jp) has performed the world’s first one-pot synthesis of conjugated polyenes, which normally require at least seven steps by conventional methods. This…

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Chementator Briefs

Glycolic acid Researchers from the group of professor Miho Yamauchi at the International Institute for Carbon-Neutral Energy Research (I2CNER) of Kyushu University (Fukuoka City, Ito Campus, i2cner.kyushu-u.ac.jp) have fabricated a liquid flow-type electrolyzer that can continuously produce an alcohol from…

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A bio-based caprolactam joint-development project is now underway

Last month, Genomatica (San Diego, Calif.; www.genomatica.com) and Aquafil (Trento, Italy; www.aquafil.com) announced a partnership to commercialize a Genomatica process for making caprolactam derived from renewable feedstocks, rather than from petroleum. The cyclic amide caprolactam is a key intermediate for…

Wastewater treatment with peracetic acid

In what is said to be the largest municipal wastewater application using peracetic acid (PAA) disinfectant to date, the Metro Wastewater Reclamation District in Denver, Colo. recently began disinfecting wastewater effluent with a PAA formulation from Enviro Tech Chemical Services,…

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A promising catalyst for low-temperature ammonia synthesis

Researchers led by professor Hideo Honoso at Tokyo Institute of Technology (Yokohama City, Japan; www.titech.ac.jp) have discovered a new catalyst that enhances the efficacy of NH3 synthesis by two orders of magnitude over that of a conventional Ru catalyst at…

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Catalytic conversion of sugars to acrylonitrile

Acrylonitrile (ACN) — a precursor in nearly all carbon fibers — is typically produced from propylene and ammonia, but a new method uses biomass-derived second-generation sugars. The process was developed by Southern Research (Durham, N.C.; www.southernresearch.org) and seeks to provide…