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Artificial enzyme shows multiple selectivity

Professor Kazuaki Ishigreo and colleagues at Nagoya University (Nagoya, Japan; http://en.nagoya-u.ac.jp) have shown that a chiral, supramolecular, U-shaped, boron Lewis acid catalyst (diagram) promotes the unprecedented multi-selective Diels–Alder reaction of propargyl aldehyde with cyclic dienes. The Diels–Alder reaction, which is…

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Industrial-grade salt recovery from zero-liquid-discharge process

A process that increases the water-recovery from reverse osmosis (RO) while producing a salt byproduct is being developed by Hyrec (Urla/Izmir, Turkey; www.hyrec.co). The process, which uses osmotically assisted RO (OARO), could be especially beneficial in coal-to-chemicals (CTC) plants in…

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Chementator Briefs

New PDH capability A new catalyst for propane dehydrogenation (PDH) that does not include precious metals has been developed by KBR Inc. (Houston, Tex.; www.kbr.com). The new catalyst is incorporated into KBR’s new PDH technology, known as K-PRO, which was…

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Making jet fuel from wood

Last month, construction began on a demonstration facility that integrates high-performance entrained-flow gasification technology and Fischer-Tropsch (F-T) synthesis for making jet fuel from woody biomass. The demonstration project is being carried out by a Japanese consortium, led by Mitsubishi Hitachi…

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Transforming plastic waste into useful aerogels

Plastic-bottle waste is toxic and non-biodegradable, and has become a major environmental issue. It often ends up in the oceans, affecting marine life, or in landfills, contaminating groundwater and affecting land use. Now a team led by professors Nhan Phan-Thien…

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Recovering rare-earth elements from coal byproducts

A team from the University of Kentucky (Lexington, Ky.; www.uky.edu) and Virginia Polytechnic Institute (Blacksburg, Va.; www.vt.edu) has set up a novel pilot plant to recover rare-earth elements (REEs) from coal-based sources, aiming to produce high-grade REE concentrates from coal-based…

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A catalyst that mimics enzymes

A research team from the University of New South Wales (Sydney, Australia; www.unsw.edu.au) and Ruhr-Universität Bochum (Bochum, Germany; www.ruhr-universität-bochum.de) has succeeded in transferring structural characteristics of natural enzymes to metallic nanoparticles, achieving high catalytic activity. In the case of enzymes,…

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Simpler, more selective scandium recovery

Rare-earth elements (REEs), such as scandium, are in high demand, but it is often difficult to economically recover and extract them. Now, II-VI Inc. (Saxonburg, Pa.; www.ii-vi.com) has developed a patent-pending process utilizing selective ion recovery (SIR) that enables highly…

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Chementator Briefs

Renewable jet fuel At the end of last October, euglena Co. (Tokyo, Japan; www.euglena.jp) completed the construction of Japan’s first demonstration plant for the production of renewable jet and diesel fuel in Yokohama. The $58-million pilot plant, located at the…

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A methane fuel cell that operates at lower temperatures

Existing methane fuel cells typically require high (750–800°C) temperatures to activate methane in a separate methane reformer that creates hydrogen gas. Now researchers at the Georgia Institute of Technology (Georgia Tech; Atlanta; www.gatech.edu) have developed a solid oxide fuel cell…