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Underground oxidation of hydrocarbons and gas separation yields hydrogen

A process for in-situ oxidation of hydrocarbons in low-quality oilfields, and subsequent gas separation, offers a path to generating hydrogen for fuel and chemicals that avoids any greenhouse gas emissions. Known as Hygienic Earth Energy (HEE), the process has been…

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Reduction of carbon dioxide to methane

Electrochemical reduction of carbon dioxide to hydrocarbons and oxygenates on copper involves reduction to a carbon monoxide adsorbate followed by transformation to hydrocarbons and oxygenates. To ensure the sustainability of the process, the electrochemical CO2 reduction is typically conducted in…

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Multi-state switchable stationary phase for chiral separation

High-pressure liquid chromatography (HPLC) using a chiral stationary phase (CSP) is the most effective method for separating enantiomers of chiral molecules. However, the limited number of CSPs available puts a constraint on applying this technology universally. Now, researchers from the…

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Ionic liquids enable lower-cost desalination with forward osmosis

Membrane-based forward osmosis (FO) desalination could be a lower-cost alternative to conventional reverse osmosis (RO) technology, which can desalinate ocean water effectively, but requires electricity to drive the separation, and so remains expensive. Scientists from Lawrence Berkeley National Laboratory (LBL;…

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Engineered microbes convert C1 feedstocks into longer-chain chemicals

Researchers at the University of South Florida (USF; Tampa, Fla.; www.usf.edu) have developed a microbial metabolic pathway that allows enzymatic conversion of one-carbon compounds into multi-carbon intermediate chemicals. The bioconversion process, which takes place in genetically engineered bacteria, could enable…

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Collaborative wastewater project points the way to improved phosphorus removal

Removal of phosphorus and other nutrients from wastewater is critical to preventing harmful algal blooms in coastal waters. Enhanced biological phosphorus removal (EBPR) — which relies on microbial communities that consume phosphate, reducing its concentration in the wastewater — has…

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Incorporating nanoparticles into polymer melts

Because of their large surface area per unit mass, nanoparticles of additives can have a big impact on the properties of plastics, such as changing the crystallization temperature, and improving heat transfer, electrical properties (conductivity) and mechanical properties, as well…

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Products from natural gas

Linde Engineering (Pullach, Germany; www.linde-engineering.com) has developed a process to recover helium, hydrocarbons and purified carbon dioxide from natural gas, while conditioning the natural gas for pipeline transport by adjusting the water and heavy-hydrocarbon dew point and the CO2 concentration.…

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Making solar steam and salts from brine

A low-cost “green” technology for water desalination and zero liquid discharge of industrial wastewater that has been drawing increasing attention is solar steam generation using nanostructured photothermal materials. However, the crystallization of salts on the surface of photothermal materials during…

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Chementator Briefs

Carbyne transfer Marcos G. Suero and his research group at the Institute of Chemical Research of Catalonia (ICIQ; Tarragona, Spain; www.iciq.es) have reported a new reaction that inserts a monovalent carbon unit between both sp2-hybridized carbons of alkenes. For the…