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Combined CO2 mitigation and H2S removal

Last month at the Global Refining Summit (Rotterdam, the Netherlands; May 17–19), Swapsol Corp. (Monmouth Junction, N.J.; www.swapsol.com) introduced a completely new sour-gas-cleanup process that reduces hydrogen sulfide levels below detectable levels (under 4 ppb) while reacting with carbon dioxide…

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H2 unit combines production, purification and compression

A recently developed hydrogen generation unit combines an autothermal, fluidized-bed methane reformer with a metal hydride compressor. Aside from combining the reforming, H2 separation and compression, which are part of conventional H2 generation (top diagram), the engineers behind the system…

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May Chementator briefs

  A new Cl2 process Oxygen-depolarized cathodes (ODCs) will be used for the first time to produce chlorine on an industrial scale in a 20,000 metric ton per year (m.t./yr) electrolyzer at the Krefeld-Uerdingen chemical park in Germany. The plant…

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This new process makes biogasoline from carbohydrates

In late March, the world’s first demonstration plant for converting sugars directly into gasoline started up at the Madison, Wisc., facilities of Virent Energy Systems, Inc. (www.virent.com). The demonstration plant — part of a joint R&D collaboration of Virent and…

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A process that makes ‘green jet fuel’ is slated for commercialization

Honeywells UOP LLC (Des Plaines, Ill.; www.uop.com) has developed a process that makes a renewable, “drop-in” jet fuel from sustainable oils, including camelina, tallow, jatropha or algae. Similar to the the UOP/Eni Ecofining process for making Green Diesel fuel (CE,…

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Bioethanol as a feedstock for ‘green’ polymers

Efforts to make a completely sustainable route to polymers based on vinyl acetate monomer (VAM) are progressing at Wacker Chemie AG (Munich, Germany; www.wacker.com). VAM — a precursor for polyvinyl acetate and ethylene-vinyl-acetate copolymers used for making dispersible polymer powders…

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Revamped hydrotreater co-processes light gas oil and tall oil derivative to produce ULSD

Co-processing of biomass-derived feed with petroleum feed for the production of diesel fuel is a tricky business, given that the former (unlike petroleum) contains oxygen. The oxygenates can be removed by hydrotreating, which converts the biofeed to normal paraffins, but…

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Destroy HFCs and recover CaF2 with this process

A process that destroys hydrofluorocarbons (HFCs) and recovers high-purity calcium fluoride has been developed by chemical-engineering professor Hideki Yamamoto at Kansai University (Suita City, Osaka; www.cheng.kansai-u.ac.jp/Process) in cooperation with Shiraishi Kogyo Kaisha Ltd. (Amagasaki City, Osaka; both Japan; www.shiraishi.co.jp/kogyo). The technology…

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Distillation-tray downcomer design improves mass transfer efficiency

A new approach to the design of the downcomer portion of distillation column trays — presented at the recent American Institute of Chemical Engineers (AIChE) Spring 2010 meeting (San Antonio, Tex.; March 21–25) — promotes a uniform fluid flow pattern,…

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Surface-structured RO membrane couples fouling resistance with flux

Engineers at the University of California–Los Angeles (UCLA; www.ucla.edu) have developed a new class of highly permeable reverse-osmosis (RO) membranes for water desalination that incorporates a “brush layer” of hydrophilic polymer chains anchored to the membrane surface. Brownian motion of…