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A bi-metallic nanocluster catalyst for highly selective asymmetric C–C formation

Shu Kobayashi and his research group at the University of Tokyo (Japan; www.chem.s.u-tokyo.ac.jp/users/synorg/index_e.html) have developed a ruthenium-silver nanocluster catalyst for the highly selective 1,4-addition reaction for the formation of asymmetric carbon-carbon bonds. Previously, the group had used its polymeric incarceration…

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Making graphene oxide in ‘a microwave’

Microwave irradiation of graphite has been shown to produce graphene oxide with 90% yield by the research group of professor Yuta Nishina, Research Core for Interdisciplinary Sciences, Okayama University (Okayama, www.tt.vbl.okayama-u.ac.jp/archives/809). The yield is not only nearly twice that obtained…

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A renewable source for methane

Conventional methanation — the reaction of CO and H2 (synthesis gas) to form methane — has recently become important as a way to produce substitute natural gas (SNG) from gasified coal in regions of the world where natural gas is…

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Making cork-like monoliths from graphene

A team from Monash University (Melbourne, Australia; www.monash.edu.au) has prepared graphene monoliths with a cork-like hierarchical structure, exhibiting ultra-low density, superelasticity, good electrical conductivity and high efficiency of energy absorption. The ability to maintain structural integrity upon large deformation is…

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A recipe for improved Ti extraction from ilmenite

Existing metallurgical processes for titanium production from ilmenite — by far the most sought-after titanium ore — are plagued by disadvantages, mainly the generation of large amounts of waste, and improvements are needed to treat ilmenite for the production of…

A step toward mineralizing CO2 captured from fluegas

Researchers from Newcastle University (U.K.; www.ncl.ac.uk) have discovered that, in the presence of a nickel catalyst, CO2 can be rapidly and cheaply converted into solid carbonate salts. The discovery could lead to a simpler and less-expensive alternative for carbon capture…

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Replacing a pressurization blower with a turbocharger reduces energy use

Reductions in power consumption by over 30% have been observed at a full-scale formaldehyde production plant by introducing a new design in which a pressurization blower is replaced by a turbocharger that is powered by the exhaust gas from the…

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This molecular sieve has a trapdoor to selectively pass CO2

An Australian team has developed a new molecular sieve that allows carbon dioxide molecules to be trapped and stored. Contrary to the way molecular sieves usually work, allowing smaller molecules through, the new sieve acts like a trapdoor, and allows…

Oxidation-based water-reuse technology that improves mass transfer

A water-recycling system for the oil-and-gas industries developed by Ecosphere Technologies Inc. (Stuart, Fla.; www.EcosphereTech.com) is designed to destroy bacteria and control corrosion in high-volume wastewater-treatment applications using a proprietary oxidation process. The technology, called Ozonix, improves the mass-transfer efficiency…

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Chementator Briefs

Nitrogen fixation The research groups of Yoshiaki Nishibayashi at the University of Tokyo (Japan; park.itc.u-tokyo.ac.jp/nishiba) and Kazunari Yoshizawa at Kyushu University (Fukuoka, Japan; trout.scc.kyushu-u.ac.jp/yoshizawaJ/indexe.html) have demonstrated the production of silylamine [N(SiMe3)3] from nitrogen gas using an iron-based catalyst. The reaction…