The research group of Shigeki Matsunaga, associate professor at the University of Tokyo (Japan; www.f.u-tokyo.ac.jp/~kanai), in collaboration with Ken Sakata at Hoshi University, has developed a new Co-based catalyst system that outperforms the existing rhodium-based catalyst system for the production…
The potential usefulness of 1,1-di-substituted alkenes for making performance polymers has been recognized for some time, but commercialization has been elusive because of the reactive nature of the monomers. Startup company Sirrus Inc. (Loveland, Ohio; www.sirruschemistry.com) has developed technology to…
A less expensive process for producing biodegradeable polyhydroxyalkanoate (PHA) plastics from renewable feedstocks is being scaled up by a factor of six, resulting in a 30,000–60,000-lb/mo pilot facility. The improved PHA process — developed by Meredian Inc. (Bainbridge, Ga.; www.meredianpha.com)…
New bio-based polyimides (PIs) that withstand temperatures up to 390°C — the highest ever reported for a bioplastic — have been developed by Tatsuo Kaneko at the Japan Advanced Institute of Science and Technology (JAIST, Nomi City; www.jaist.ac.jp), in collaboration…
A new thermoset polymer has been discovered by researchers at IBM Research Almaden (San Jose, Calif.; www.research.ibm.com). The new material, polyhexahydrotriazine (PHT), has a very high Young’s Modulus (up to 14 GPa, compared with a Young’s Modulus of 4 GPa…
NEC Corp. (Tokyo, Japan; www.nec.com) has developed a two-stage, heterogeneous synthesis for making a high-functionality bioplastic (70 wt.% plant content) from non-edible plant cellulose. The new bioplastic is said to have excellent thermo-plasticity (275 MFR), heat resistance (140°C glass transition…
While super glassy polymers are initially very porous and ultra-permeable — a property that makes them suitable as gas-separation membranes — they quickly pack into a denser phase becoming less porous and permeable. Now, new materials that prevent such aging…
Oil-water separation A complex formed by combining maleic anhydride copolymers with a cationic fluorosurfactant can separate oil from water when coated on a wire mesh. Researchers at Durham University (U.K.; www.durham.ac.uk) devised a method of preparing the complex in…
Biosynthetic Technologies (Irvine, Calif.; www.biosynthetic.com) has developed a continuous-flow process to convert any animal- or plant-based fatty acids with high oleic-acid content into synthetic esters that can be used in formulations for motor oils and industrial lubricants. These biosynthetic esters…
Last month, The Linde Group (Pullach, Germany; www.linde.com) and BASF SE (Ludwigshafen, Germany; www.basf.com) announced plans to cooperate in developing and licensing processes for the on-purpose production of linear butenes and butadiene. BASF has developed process technology and catalysts as…