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A two-step process for making graphene

A Korean team has developed a carbon material that is as effective as graphene in applications, such as solar cells and semiconductor chips, using a process that requires only two steps instead of the usual eight. High-quality graphene is usually…

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A sorbent that enhances the water-gas shift reaction

Scientists at the National Energy Technology Laboratory (NETL; Morgantown, W. Va.; www.netl.doe.gov) have demonstrated a process for enhancing the efficiency of the water-gas shift (WGS) reaction. The process revolves around a magnesium hydroxide sorbent material that can remove CO2 from…

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Platform for reactive monomers enables short cure times for coatings

The potential usefulness of 1,1-di-substituted alkenes for making performance polymers has been recognized for some time, but commercialization has been elusive because of the reactive nature of the monomers. Startup company Sirrus Inc. (Loveland, Ohio; www.sirruschemistry.com) has developed technology to…

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An improved PHA-bioplastic process is scaled up

A less expensive process for producing biodegradeable polyhydroxyalkanoate (PHA) plastics from renewable feedstocks is being scaled up by a factor of six, resulting in a 30,000–60,000-lb/mo pilot facility. The improved PHA process — developed by Meredian Inc. (Bainbridge, Ga.; www.meredianpha.com)…

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This inexpensive bioplastic takes the heat

New bio-based polyimides (PIs) that withstand temperatures up to 390°C — the highest ever reported for a bioplastic — have been developed by Tatsuo Kaneko at the Japan Advanced Institute of Science and Technology (JAIST, Nomi City; www.jaist.ac.jp), in collaboration…

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New polymer is said to be first-ever recyclable thermoset

A new thermoset polymer has been discovered by researchers at IBM Research Almaden (San Jose, Calif.; www.research.ibm.com). The new material, polyhexahydrotriazine (PHT), has a very high Young’s Modulus (up to 14 GPa, compared with a Young’s Modulus of 4 GPa…

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A new route to a cellulose-based bioplastic

NEC Corp. (Tokyo, Japan; www.nec.com) has developed a two-stage, heterogeneous synthesis for making a high-functionality bioplastic (70 wt.% plant content) from non-edible plant cellulose. The new bioplastic is said to have excellent thermo-plasticity (275 MFR), heat resistance (140°C glass transition…

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A polymer for longer-lasting membranes

While super glassy polymers are initially very porous and ultra-permeable — a property that makes them suitable as gas-separation membranes — they quickly pack into a denser phase becoming less porous and permeable. Now, new materials that prevent such aging…

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July Chementator Briefs

  Oil-water separation A complex formed by combining maleic anhydride copolymers with a cationic fluorosurfactant can separate oil from water when coated on a wire mesh. Researchers at Durham University (U.K.; www.durham.ac.uk) devised a method of preparing the complex in…

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This fatty-acid conversion process results in synthetic lubricant base oils

Biosynthetic Technologies (Irvine, Calif.; www.biosynthetic.com) has developed a continuous-flow process to convert any animal- or plant-based fatty acids with high oleic-acid content into synthetic esters that can be used in formulations for motor oils and industrial lubricants. These biosynthetic esters…