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Lignin to adipic acid

A new study from the National Renewable Energy Laboratory (NREL; Golden, Colo.; www.nrel.gov) demonstrates the conversion of lignin-derived compounds to adipic acid, an important precursor for making nylon and other chemicals. The new route offers a “greener” alternative to conventional…

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Biomass pretreatment approach can reduce enzyme requirements

Biomass is a recalcitrant, heterogeneous matrix of cellulose, hemicellulose and lignin that resists microbial and enzymatic breakdown. Overcoming this recalcitrance is the major economic barrier to the conversion of biomass to sugars or other chemicals. Heat, acid and other chemicals…

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Making fuels from almost any organic material

Adgex Ltd. (Sydney, Australia; www.adgex.com) is marketing a plant, tradenamed “Green Blaze,” for processing organic raw materials by means of high-speed ablative pyrolysis. According to the company, the plant (flowsheet) can be adapted to convert into synthetic fuel almost any…

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End-to-end demonstration of CO2-to-ethanol process achieved

Joule Unlimited (Bedford, Mass.; www.jouleunlimited.com) announced recently that it has achieved end-to-end production of ethanol from carbon dioxide and sunlight (CO2-to-ethanol), using its specially designed photobioreactor and engineered cyanobacteria. The full production runs occurred late last year at the company’s…

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Modified MOFs could cut carbon-capture costs in half

Chemists from the University of California, Berkeley (UC Berkeley; www.berkeley.edu) have modified a metal-organic framework (MOF) compound with diamines, which enables the material to be tuned to absorb CO2 at different temperatures, such as from air at room temperature, or…

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MOF material improves CO2-capture effectiveness

Industrial CO2 capture is currently done by absorption in liquid amines, such as monoethanolamine. However, absorption-based carbon capture carries a significant energy penalty for regenerating CO2 in a stripping column — power plants can lose 20–30% of their energy output…

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A new primary aluminum-production process to be piloted

Last month, Hydro ASA (www.hydro.com) entered into a contract with Multiconsult (both Oslo, Norway; www.multionsult.no) for engineering services for Hydro’s planned pilot plant at Karmøy, Norway. The Karmøy pilot aims to verify what Hydro calls the worlds most energy- and…

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Making bio-based PET monomer from furfural

The research group of Yuya Tachibana at Gunma University (Gunma, Japan; greenpolymer.chem-bio.st.gunma-u.ac.jp) has developed a procedure for the production of terephthalic acid (TPA), the monomer of the widely used thermoplastic polymer polyethylene terephthalate (PET), from the inedible biomass-derived starting material…

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A patented process makes stabilized proteins

XstalBio Ltd. (Glasgow, U.K.; www.xstalbio.com) has recently been issued a patent (US 8,932,715) covering the use of precipitation-stabilizing additives for the manufacture of dry powders of therapeutic proteins, including monoclonal antibodies (mAbs). Compared to lyophilization, the XstalBio precipitation process offers…

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Scaleup for an alternative route to PC monomer

Earlier this year, Asahi Kasei Chemicals Corp. (Tokyo, Japan; www.asahi-kasei.co.jp/chemicals) has developed a new process for making diphenyl carbonate (DPC), a monomer used for making polycarbonate (PC) resins. This new route to DPC uses only an alcohol, phenol and CO2…