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Reduction of carbon dioxide to methane

Electrochemical reduction of carbon dioxide to hydrocarbons and oxygenates on copper involves reduction to a carbon monoxide adsorbate followed by transformation to hydrocarbons and oxygenates. To ensure the sustainability of the process, the electrochemical CO2 reduction is typically conducted in…

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Multi-state switchable stationary phase for chiral separation

High-pressure liquid chromatography (HPLC) using a chiral stationary phase (CSP) is the most effective method for separating enantiomers of chiral molecules. However, the limited number of CSPs available puts a constraint on applying this technology universally. Now, researchers from the…

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Ionic liquids enable lower-cost desalination with forward osmosis

Membrane-based forward osmosis (FO) desalination could be a lower-cost alternative to conventional reverse osmosis (RO) technology, which can desalinate ocean water effectively, but requires electricity to drive the separation, and so remains expensive. Scientists from Lawrence Berkeley National Laboratory (LBL;…

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Engineered microbes convert C1 feedstocks into longer-chain chemicals

Researchers at the University of South Florida (USF; Tampa, Fla.; www.usf.edu) have developed a microbial metabolic pathway that allows enzymatic conversion of one-carbon compounds into multi-carbon intermediate chemicals. The bioconversion process, which takes place in genetically engineered bacteria, could enable…

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Collaborative wastewater project points the way to improved phosphorus removal

Removal of phosphorus and other nutrients from wastewater is critical to preventing harmful algal blooms in coastal waters. Enhanced biological phosphorus removal (EBPR) — which relies on microbial communities that consume phosphate, reducing its concentration in the wastewater — has…

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Integrated e-waste processing facility nears completion

Although it contains many valuable metals, electronic waste (e-waste) is an exceedingly difficult material stream to process, and the vast majority of e-waste is not recycled. EnviroLeach Technologies Inc. (Vancouver, B.C.; www.enviroleach.com) is currently preparing to start up a first-of-its-kind…

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This multifunctional photocatalyst splits water with visible light

Oxysulfide semiconductors have narrow bandgaps — a property that makes them suitable photocatalysts for water splitting under irradiation with visible light (640 nm wavelength). That’s because the electronegative sulfide ions negatively shift the valence band edges of the corresponding oxides.…

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The outlook for hydrogen as an energy carrier

Many countries are now making rapid advances in hydrogen energy technologies and strategy, and the rest of the world has much to learn from their experience, according to a new report — Advancing Hydrogen — compiled by a team from…

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These magnetic ‘nanosprings’ decompose microplastics

Microplastics — a subgroup of plastics with an effective diameter less than 5 mm — are ubiquitous pollutants. They adsorb organic and metal pollutants that are ingested by aquatic organisms, and accumulated all the way up the food chain. Using…

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New research solves debate over water-gas shift reaction mechanism

The water-gas shift reaction (WGS; in which water vapor is reacted with carbon monoxide over a copper-chromium-iron-oxide catalyst to yield hydrogen and CO2) is of paramount importance to the chemical industry, as it is a primary route to producing H2…