Processing & Handling
Silicate-rock-based material can replace flyash in cement, lowering costs and CO2
Flyash, a waste byproduct from coal burning, has been used effectively as a supplementary cementitious material (SCM) in Portland cement to displace a portion of the cement and lower the CO2 emissions associated with cement making. But because coal burning…
A new electrolyte supercharges sodium-ion batteries
Sodium-ion batteries have many advantages over lithium-ion batteries due to sodium’s abundance and low cost. However, there are several performance challenges to overcome with sodium-ion batteries because there is typically a tradeoff between energy density and lifecycle. Now, a research…
A step closer to transition-metal catalysis with aluminum
Chemists from the Institute of Inorganic and Analytical Chemistry at the University of Freiburg (Germany; uni-freiburg.de) have synthesized a cationic, low-valence aluminum complex salt. “So far, there has been only one example of a cationic, low-valent aluminum compound, but it…
Chementator briefs
Zero-spin Silicon Natural silicon consists of three isotopes: 28Si (92.2%) and 30Si (3.1%) — each with zero electron spin state — and 29Si (4.7%) with a spin state of one half. The presence of 29Si in concentrations above 500 parts…
Biodegradable corn-based adhesive is non-toxic, with tunable properties
A new class of adhesives being developed by the startup gluECO Adhesives LLC (Ashburnham, Mass.; www.glueco-adhesives.com) is based on corn proteins and has a host of environmentally friendly properties, such as biodegradability and the ability to be easily removed in…
Chementator Briefs
Biomethane Last month, NextChem, a subsidiary of Maire Tecnimont S.p.A. (Rome, Italy; www.mairetecnimont.com) was awarded a contract by ENGIE subsidiary Storengy (Bois-Colombes Cedex, France; www.storengy.com) to perform an advanced basic-engineering study for a plant that will produce second-generation biomethane from…
A more-sensitive way to differentiate chiral compounds
Circular dichroism (CD) is the established method for distinguishing between enantiomers — the optical isomers of molecules that are mirror images of each other. In this approach, circularly polarized light is passed through the sample and is absorbed differently by…
Upcycling of waste ABS into 3D-printable material with enhanced properties
In an advancement toward circularity for commodity plastics, researchers at the Oak Ridge National Laboratory (ORNL; Oak Ridge, Tenn.; www.ornl.gov) have developed a method for upcycling the commodity thermoplastic acrylonitrile butadiene styrene (ABS) into an ABS-vitrimer material that can be…
Limpet tooth inspires strongest biomaterial
An interdisciplinary team of biologists, chemists and engineers from the University of Portsmouth (U.K.; www.port.ac.uk) have become the first to successfully grow a limpet-inspired biomaterial with extreme strength. The common limpet (Patella vulgata) is a small, snail-like mollusk with a…
Biosynthesis of renewable, high-energy-density, cyclopropane-based fuels
Cyclopropane-functionalized hydrocarbons can be excellent fuels because of their high energy densities, but organic synthesis of such fuels is difficult. In work recently published in the journal Joule, a research team led by Jay Keasling at the Joint Bioenergy Institute…