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Processing & Handling

Silicate-rock-based material can replace flyash in cement, lowering costs and CO2

Flyash, a waste byproduct from coal burning, has been used effectively as a supplementary cementitious material (SCM) in Portland cement to displace a portion of the cement and lower the CO2 emissions associated with cement making. But because coal burning…

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A new electrolyte supercharges sodium-ion batteries

Sodium-ion batteries have many advantages over lithium-ion batteries due to sodium’s abundance and low cost. However, there are several performance challenges to overcome with sodium-ion batteries because there is typically a tradeoff between energy density and lifecycle. Now, a research…

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A step closer to transition-metal catalysis with aluminum

Chemists from the Institute of Inorganic and Analytical Chemistry at the University of Freiburg (Germany; uni-freiburg.de) have synthesized a cationic, low-valence aluminum complex salt. “So far, there has been only one example of a cationic, low-valent aluminum compound, but it…

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Chementator briefs

Zero-spin Silicon Natural silicon consists of three isotopes: 28Si (92.2%) and 30Si (3.1%) — each with zero electron spin state — and 29Si (4.7%) with a spin state of one half. The presence of 29Si in concentrations above 500 parts…

Energy costs cut by 50% for high-strength aluminum alloys

Aluminum alloy 7075 has excellent mechanical properties, including high strength for lightweighting applications, but its production process is energy intensive, which raises costs and limits its use. Now, scientists at Pacific Northwest National Laboratory (PNNL; Richland, Wash.; www.pnnl.gov) have developed…

Zero-CO2 ethane cracker technology is available commercially

A next-generation ethane-feed steam cracker designed by Lummus Technology (Houston; www.lummus.com) has the ability to achieve zero carbon dioxide emissions in the production of ethylene. The zero-CO2 design utilizes Lummus SRT pyrolysis furnaces and a state-of-the-art product-recovery system. Lummus improved…

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Extracting pressurized hydrogen from ammonia, methane and biogas

Proton ceramic cells that couple endothermic steam reforming with heat from electrochemical gas separation and compression have been scaled up. These cells, developed by CoorsTek Membrane Sciences AS (Oslo; www.coorstek.com), the University of Oslo (both Norway; www.uio.no) and the Institute…

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Facts At Your Fingertips: Gas Dispersion in Liquids

Injecting gases through a diffuser into a liquid is an important aspect of many operations in the chemical process industries (CPI). Important applications include dissolving reactant gases into a liquid phase for further reaction (such as in hydrogenation, oxidation, ozonation),…

Biosynthesis of renewable, high-energy-density, cyclopropane-based fuels

Cyclopropane-functionalized hydrocarbons can be excellent fuels because of their high energy densities, but organic synthesis of such fuels is difficult. In work recently published in the journal Joule, a research team led by Jay Keasling at the Joint Bioenergy Institute…

Achieving Balance in Combustion

New hardware combined with monitoring technologies can help optimize combustion now and in the carbon-conscious future Combustion has long been a delicate balancing act. Chemical processors want their combustion systems to be fuel efficient and available for use, while at…